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上海电力大学学报:1995,11(2):10-17
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电沉积CuInSe2上H2O2阴极还原时产生的电化学振荡行为(Ⅱ)
(1.上海电力学院;2.上海大学)
Oscillating Behaviour on Electrodeposited CuInSe2 Thin Films during H2O2 Catholic Reduction
(1.Shanghai Institute of Electric Power;2.Shanghai University)
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投稿时间:1995-03-14    
中文摘要: 本文研究了电沉积制得的CuInSe2薄膜在阴极还原H2O2时产生的电化学振荡行为, 一方面对影响该振荡行为的一些因素如振荡溶液组成、传质、光照等进行了分析;另一方面采用外界周期性光照和外接小幅度正弦波电位来调节振荡频率, 使光电信号调制振荡趋向成熟.这为CuInSe2半导体发展成为光电传感器件提供了一定的理论与实践基础.
中文关键词: CuInSe2  H2O2  阴极还原  电化学振荡  光电化学
Abstract:In this paper, we study the electrochemistry oscillation phenomenna on electrodeposited CuInSe2 thin films electrode during H2O2cathodic reduction. On one hand, we study and analyse the factor; that affect the oscillating behaviour, including the composition of oscillating solution, mass transport and illununation. On the other hand, we discovered that the frequency of oscillation could be controlled by external periodic light and external small potential modulation. This fact may open new opportunities for photoelectric sensors with CuInSe2.
文章编号:19950202     中图分类号:    文献标志码:
基金项目:国家自然科学基金;厦门大学固体表面物理化学国家重点实验室资助项目
引用文本:
徐群杰,高永丰,邓薰南.电沉积CuInSe2上H2O2阴极还原时产生的电化学振荡行为(Ⅱ)[J].上海电力大学学报,1995,11(2):10-17.
Xu Qun-jie,Gao Yong-feng,Deng Xun-nan.Oscillating Behaviour on Electrodeposited CuInSe2 Thin Films during H2O2 Catholic Reduction[J].Journal of Shanghai University of Electric Power,1995,11(2):10-17.