Ce<sup>3+</sup>聚苯胺/蒙脱土复合材料掺杂环氧涂层的制备及耐腐蚀性能

张大全; 朱力华; 章振华; 高立新

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DOI:10.3969/j.issn.1006-4729.2016.04.010

上海电力大学学报:2016,32(4):355-361

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Ce³⁺聚苯胺/蒙脱土复合材料掺杂环氧涂层的制备及耐腐蚀性能

张大全, 朱力华, 章振华, 高立新

(上海电力学院环境与化学工程学院)

Preparation and Corrosion Protection of Epoxy Coating Doped with Ce³⁺-Polyaniline/Montmorillonite Composites

ZHANG Daquan, ZHU Lihua, ZHANG Zhenhua, GAO Lixin

(School of Environmental and Chemical Engineering, Shanghai University of Electric Powder, Shanghai 200090, China)

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投稿时间：2015-09-30

中文摘要: 采用原位插层聚合法合成了聚苯胺/蒙脱土复合材料（PANI/MMT），通过阳离子交换吸附制得了Ce³⁺-聚苯胺/蒙脱土复合材料（Ce³⁺-PANI/MMT）.随后对所制备的样品进行表征.将PANI，PANI/MMT，Ce³⁺-PANI/MMT粉末添加到环氧树脂中（质量分数为5%），涂覆在碳钢表面，干燥.将4种涂层浸泡在3.5% NaCl溶液中，通过电化学实验来比较4种涂层的耐蚀性能.研究结果表明，Ce³⁺-PANI/MMT复合材料掺杂的环氧涂层的耐腐蚀性能最好，且具有一定的自修复性能.

中文关键词: 聚苯胺蒙脱土铈离子耐腐蚀自修复

Abstract:Polyaniline/organophilic montmorillonite nanocomposite materials are successfully synthetized by in situ intercalative polymerization.Ce³⁺-PANI/MMT nanocomposite materials (Ce³⁺-PANI/MMT) are prepared by cation exchange adsorption.The as-prepared samples are subsequently characterized.Epoxy coatings containing PANI,PANI/MMT and Ce³⁺-PANI/MMT powders are coated on the surface of carbon steel.The corrosion performance of the coatings are evaluated by electrochemical corrosion experiment in 3.5% NaCl.It is showed that the epoxy coating containing Ce³⁺-PANI/MMT composites has a better performance and a self-healing effect against steel corrosion on the coating defects.

keywords: polyaniline montmorillonite cerium ion anticorrosion self-healing

文章编号：20160410 中图分类号： 文献标志码：

基金项目:上海市基础研究重点项目（11JC1404400）.

作者	单位	E-mail
张大全	上海电力学院环境与化学工程学院	zhangdaquan@shiep.edu.cn
朱力华	上海电力学院环境与化学工程学院
章振华	上海电力学院环境与化学工程学院
高立新	上海电力学院环境与化学工程学院

引用文本：
张大全,朱力华,章振华,等.Ce³⁺聚苯胺/蒙脱土复合材料掺杂环氧涂层的制备及耐腐蚀性能[J].上海电力大学学报,2016,32(4):355-361.
ZHANG Daquan,ZHU Lihua,ZHANG Zhenhua,et al.Preparation and Corrosion Protection of Epoxy Coating Doped with Ce³⁺-Polyaniline/Montmorillonite Composites[J].Journal of Shanghai University of Electric Power,2016,32(4):355-361.

Author Name	Affiliation	E-mail
ZHANG Daquan	School of Environmental and Chemical Engineering, Shanghai University of Electric Powder, Shanghai 200090, China	zhangdaquan@shiep.edu.cn
ZHU Lihua	School of Environmental and Chemical Engineering, Shanghai University of Electric Powder, Shanghai 200090, China
ZHANG Zhenhua	School of Environmental and Chemical Engineering, Shanghai University of Electric Powder, Shanghai 200090, China
GAO Lixin	School of Environmental and Chemical Engineering, Shanghai University of Electric Powder, Shanghai 200090, China