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上海电力大学学报:2006,22(3):229-232
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模拟水中B30铜镍合金耐蚀性的电化学研究
(上海电力学院 能源与环境工程学院, 上海 200090)
Electrochemical Studies of Inhibition Effects for B30 Cu-Ni Alloy Corrosion in Simulated Water
(School of Thermal Power & Environmental Engineering, Shanghai University of Electric Power, Shanghai 200090, China)
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投稿时间:2006-07-04    
中文摘要: 当模拟水介质的pH在7~9之间,随着pH值的增大,B30铜镍合金的耐蚀性能增加;pH大于9时,B30铜镍合金的耐蚀性能又随pH的增大而降低.模拟水介质的温度升高,氯离子或硫离子浓度的增加,都会使B30铜镍合金的耐蚀性能降低.在模拟水中加入绿色水处理缓蚀剂复配聚天冬氨酸40mg/L时,对B30铜镍合金具有明显的缓蚀效果.
中文关键词: B30铜镍合金  腐蚀  缓蚀剂  交流阻抗
Abstract:The inhibition effects of environment-friendly inhibitors of the complex of PASP and Na2WO4 for B30 Cu-Ni alloy corrosion are studied.The results show that with the concentration of the sulfur ion and chloride ion of the simulated water,the corrosion is increasingly strengthened.Moreover,the increased temperature also accelerates the corrosion velocity for B30 Cu-Ni alloy in simulated water.The resistance of Cu-Ni alloy to the corrosion is enhanced with the increasing pH of the simulated water in the range of pH 7 and pH 9.When the pH exceeds 9,the increase of pH leads to a decrease of resistance to corrosion for B30 Cu-Ni alloy.With the total concentration of 40 mg/L for the complex inhibitors,the optimum complex ratio of PASP to Na2WO4 is 1:1 and such a complex gives a good inhibition effect.
文章编号:20060308     中图分类号:    文献标志码:
基金项目:上海市曙光计划项目(04SG55);厦门大学固体表面物理化学国家重点实验室项目(200512);国家自然科学基金项目(20406009);上海市重点学科项目(P1304);大学生科创基金项目(K2006-220)
引用文本:
徐群杰,丁茂荣,陈子超,等.模拟水中B30铜镍合金耐蚀性的电化学研究[J].上海电力大学学报,2006,22(3):229-232.
XU Qun-jie,DING Mao-Rong,CHEN Zi-chao,et al.Electrochemical Studies of Inhibition Effects for B30 Cu-Ni Alloy Corrosion in Simulated Water[J].Journal of Shanghai University of Electric Power,2006,22(3):229-232.