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投稿时间：2022-04-04
投稿时间：2022-04-04
中文摘要: 氨选择性催化还原法(NH3-SCR)是目前最高效、最成熟的烟气脱硝技术。Mn基催化剂在选择性催化还原法(SCR)中展现出很高的低温活性,具有广阔的应用前景。但实际烟气中存在的H2O和SO2会引起Mn基催化剂的中毒失效,极大限制了其工业化应用。为了突破工业化应用瓶颈,分析了低温Mn基催化剂的H2O和SO2中毒机理,综述了其抗水抗硫研究进展。研究结论可为抗水抗硫低温Mn基催化剂的开发及应用提供理论基础。
Abstract:NH3-selective catalytic reduction (SCR) is the most efficient and mature flue gas deNOx technology at present.Mn-based catalysts show high low-temperature activities in SCR reaction and have broad application prospects.However,the presence of H2O and SO2 in flue gas could cause poisoning and deactivation of Mn-based catalysts,which greatly limits its industrial applications.In order to break through the bottleneck of industrial application,the H2O and SO2 poisoning mechanism of low-temperature Mn-based catalysts is analyzed,and the research progress of H2O and SO2 resistance is reviewed.The research conclusions provide a theoretical basis for the development and application of low-temperature Mn-based catalysts with H2O and SO2 resistance.
keywords: NH3-selective catalytic reduction low-temperature Mn-based catalysts H2O resistance SO2 resistance
文章编号：20225002 中图分类号：TK09 文献标志码：
基金项目:
| 作者 | 单位 | |
| 乔宇恒 | 上海电力大学 能源与机械工程学院 | |
| 官贞珍 | 上海电力大学 能源与机械工程学院 | guanzzhen@163.com |
| 袁一帆 | 上海电力大学 能源与机械工程学院 | |
| 张梦岩 | 上海电力大学 能源与机械工程学院 |
引用文本：
乔宇恒,官贞珍,袁一帆,等.低温Mn基脱硝催化剂抗水抗硫研究进展[J].上海电力大学学报,2022,38(5):421-426.
QIAO Yuheng,GUAN Zhenzhen,YUAN Yifan,et al.Research Progress on Water and Sulfur Resistance of Low-Temperature Mn-based DeNOx Catalysts[J].Journal of Shanghai University of Electric Power,2022,38(5):421-426.
乔宇恒,官贞珍,袁一帆,等.低温Mn基脱硝催化剂抗水抗硫研究进展[J].上海电力大学学报,2022,38(5):421-426.
QIAO Yuheng,GUAN Zhenzhen,YUAN Yifan,et al.Research Progress on Water and Sulfur Resistance of Low-Temperature Mn-based DeNOx Catalysts[J].Journal of Shanghai University of Electric Power,2022,38(5):421-426.